Product
Reputable factory supply FOR-VAL-OH 4289-97-8 in stock with high standard
- Molecular Formula: C6H11NO3
- Molecular Weight: 145.158
- Vapor Pressure: 5.12E-06mmHg at 25°C
- Melting Point: 153 °C
- Refractive Index: 12 ° (C=4, EtOH)
- Boiling Point: 355.7 °C at 760 mmHg
- PKA: 3.51±0.10(Predicted)
- Flash Point: 168.9 °C
- Density: 1.124 g/cm3
FOR-VAL-OH(Cas 4289-97-8) Usage
InChI:InChI=1/C6H11NO3/c1-4(2)5(6(9)10)7-3-8/h3-5H,1-2H3,(H,7,8)(H,9,10)/t5-/m0/s1
4289-97-8 Relevant articles
Effector enhanced enantioselective hydroformylation
Bai, Shao-Tao,Kluwer, Alexander M.,Reek, Joost N. H.
supporting information, p. 14151 - 14154 (2019/12/02)
In this communication, we report rhodium...
Divergent Synthesis of Enantioenriched β-Functional Amines via Desymmetrization of meso-Aziridines with Isocyanides
Li, Xiangqiang,Xiong, Qian,Guan, Mingming,Dong, Shunxi,Liu, Xiaohua,Feng, Xiaoming
supporting information, p. 6096 - 6101 (2019/08/20)
A highly enantioselective ring-opening d...
Formyloxyacetoxyphenylmethane as an N-Formylating Reagent for Amines, Amino Acids, and Peptides
Chapman, Robert S. L.,Lawrence, Ruth,Williams, Jonathan M. J.,Bull, Steven D.
supporting information, p. 4908 - 4911 (2017/09/23)
Formyloxyacetoxyphenylmethane is a stabl...
GRAMICIDIN A MUTANTS THAT FUNCTION AS ANTIBIOTICS WITH IMPROVED SOLUBILITY AND REDUCED TOXICITY
-
Paragraph 0285, (2015/09/23)
Described herein are antimicrobial pepti...
4289-97-8 Process route
-
-
64-18-6
formic acid
-
-
72-18-4,25609-85-2,7004-03-7,921-10-8
L-valine
-
-
4289-97-8
N-formyl-L-valine
| Conditions | Yield |
|---|---|
|
formic acid; L-valine;
at 20 - 55 ℃;
With
acetic anhydride;
at 20 - 55 ℃;
for 2h;
With
water;
Heating;
Reduced pressure;
|
95%
|
|
With
acetic anhydride;
In
acetic acid;
at 20 ℃;
for 4h;
Inert atmosphere;
|
75%
|
|
With
acetic anhydride;
at 0 - 20 ℃;
|
72%
|
|
With
acetic anhydride;
at 20 ℃;
for 24h;
Cooling with ice;
|
64%
|
-
-
72-18-4,25609-85-2,7004-03-7,921-10-8
L-valine
-
-
113388-44-6
(formyloxy)(acetoxy)phenylmethane
-
-
4289-97-8
N-formyl-L-valine
| Conditions | Yield |
|---|---|
|
With
sodium hydrogencarbonate;
In
water;
at 20 ℃;
for 16h;
|
78%
|
4289-97-8 Upstream products
-
64-18-6
formic acid
-
516-06-3
D,L-valine
-
93033-04-6
N-[1-(Benzoimidazole-1-carbonyl)-2-methyl-propyl]-formamide
-
2258-42-6
formyl acetic anhydride
4289-97-8 Downstream products
-
640-68-6
D-Val-OH
-
72-18-4
L-valine
-
104743-88-6
N -formyl-DL-valine anilide
-
101496-73-5
N -(N -formyl-valyl)-phenylalanine ; optically inactive substance
